You are correct: the Nymph Cloak (and Algernon's Cloak for that matter) give a +2 bonus to CHA, but also offer the Mage spell Charm Person. The charges are limited (but it has quite a lot of charges) though. My Paladin wears the Cloak, but I never use the spell, because I don't want the Cloak to wear out (no risks on this one!)...
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