Most of the high-level spells, 6th-9th, aren't going to be sold by Orrick. You'll find most of them in lower Dorn's Deep, from Malavon and Nym, as well as some barrels outside of Malavon's building, in the Artisan's District (where all the Umber Hulks and Blind Minotaurs are).
-Wrath
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