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Yes. When you click on an NPC, if you go to barter you buy scrolls. But, some NPCs (check the temple and mage guilds in particular) have different options, one of which is spells. Those are spells you know, and the effects of those spells are what you can use for enchantment. Note that all that is necessary is to know the effect, so for example even the weakest paralyze spell would allow you to put a strong paralyze enchantment on an appropriate item.
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