Once you've clicked on USE/GIVE check the parchment scroll on bottom left - if it has a blue Use rather than Give highlighted you will have to click on Give to change to Give mode.
(And then you may have to scroll back down to the potion).
Once you have the potion with a blue Give, just Ctrl-click the toad.
Identify - Temple, Priest guild, Training you need Ancient Lore.
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