Minsc doesn't have any quests. Jaheira has a long, complex quest if you play as a male, but I don't know how much of it shows up if you're playing a female PC. Edwin has a humorous quest, which you could do along with Korgan's. Aerie doesn't have much unless she's a love interest. Viconia? Don't know. Mazzy has a brief quest. Valygar must be with you if you want to get into the planar sphere, but I had him in my party for two weeks of game time and never found another use for him (god knows he's no fighter). There is a sort of quest involving Yoshimo, and if you dont' know what I'm talking about, you won't hear it from me. Keldorn and Jan have minor quests. Anomen's quest is elaborate, and turns him into an excellent NPC if you play the good options. Haer Dalis has a quest but you can get it without him (and he's useless, so don't bother). Hmm. Who am I forgetting? I think that's it, since you already mentioned Nalia and Cernd.
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