Chaotic Commands prevents you from being stunned or dominated, but nothing you can do will prevent them from using their brain devour. Don't face them in toe-to-toe combat. There are a few methods for dealing with the illithid, all complicated and usually annoying. The first is to use a thief with some invisibility potions to backstab them. The second is to summon certain creatures which don't have any intelligence anyway, so they can't be brain devoured.
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