OK I got a party of 6 and I am curently in chapter 6 and I have already gone past the xp cap limit. Fortunatly I have got Throne of Bhaal so I carry on gaining level and have access to the High Level stuff like Whirl Wind attack and Summon Diva. So yes it is definatly possible to get to the Shadows of Amn XP cap with a party of 6, there is more than enough XP in the game to reach it.
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