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The Sunray's damage against Undead does not really count, since it is just a means to bypass the fact that Undead are immuned to instant-death effects from spells.
Hence you will see the Mace of Disruption and Azuredge do nothing spectacular when they instant-kill an Undead as they are weapons. Sunray is a spell and cannot imitate the weapons, hence the huge damage.
Jim's experiment in the link that pcgiant gave, is the single most damaging, valid and legitimate strike in the whole game.
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