Although people ping on it quite a bit...Microsoft's FrontPage is a pretty good tool for beginners and most intermediate users. You just have to be careful about using too many of the advance functions.
However, I agree...DreamWeaver takes first place in my book. But remember that Dreamweaver can be a little difficult to use for beginners as it does not offer as much "hand-holding" (and I mean that in a good way) as FrontPage does.
------------------
Now where did I leave that doughnut?!