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Spoiler
I have had this exact problem in the past. When Jaheira left my party and went to the harpers, I chased her (as you are supposed to do). When I found her, it would not allow me to talk to her. It said mind-controlled characters cannot initiate dialogue. As it turns out, I reloaded to a previous save game, she left, I followed and then she spoke to me.
It seems to be a bug in the game. I hope this helps.
Aviendha.
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