Yes, you need to be a higher level at the guild in order to learn to (bless/enchant).
For example:
In order to Bless armor or weapons you need to learn the Bless (skill)
In order to learn the Bless (skill) you need to learn the Cabalist (trait)
In order to learn the Cabalist (trait) to need to be at least Level 4
at the temple.
I expect a similar progression for the Enchant (skill)
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