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You can buy some nice items from Bernard in the Copper Coronet, although most of those won't see you to the end of the game. Also, in the Underdark there are a few good merchants in the Svirfneblin Village and in Ust Natha. And after you return from the Underdark, Ribald in the Adventurer's Mart will let you take a look at his special items.
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