If your PC is not a mage and you have a good-aligned party, I see no reason in not taking her. Her thief skills are crappy of course, but her mage powers are what make her good. She is dual-classed, which means she doesn't split experience points, and she can cast up to level 8 spells in SoA.
Imoen would be better, but when she's rescued, she's way behind in levels when compared to Nalia. However, her thieving abilities are OK - she has about 90% in find traps and open locks, the most important skills in my opinion.
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