I'd go for Ranger lvl 8/Cleric lvl 20 as your cleric skills will end up more important to you by then. Anyway I'm pretty sure you can keep adding proficiencies. When I used Anomen - dualed Fighter then Cleric - and a proficiency came up, I was able to give him a third point in Mace. Once you can use your Ranger class again I'm pretty sure you can put two points in proficiencies where applicable.
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