You can dual a ranger to cleric (at least you could in Icewind). You just have to be human. The rule is only humans can dual class. Only demi-humans can multiclass. Just be sure to put his proficiencies in weapons you can use as a cleric (sling, flail, and dual wield are the best, probably, and an offhand weapon like mace need only have one proficiency since you won't get an extra attack on your offhand anyway).
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