On the question re: stun, the only thing that can influence this is magic resistance. If your hp is less than 90 you will be affected by it, that's why it's such a great spell and that's why Celestial Fury is such a great weapon. Just hammer anything till you guess their hp drops below 90 and then cast it.
Balor is actually one of the most powerful tanar'ri around. Interestingly enough, as a joke i summoned a glabrezu and a pit fiend and had them fight, the pit fiend lost every time as the glabrezu were immune to all of his attacks and the pit fiend wasn't immune to the glabrezu's attacks. Pit fiends are actually devils, not demons.
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