I have the Collector's edition, which comes with a bonus CD. The bonus CD only contains audiotracks and promotional materials (nothing that you would not find on websites). The collectors edition, does have an extra store in the Adventure's Mart. The store is way cool, especially for Planescape: Torment fans such as myself. They sell items such as the Zerth Blade of Dakkan, Vaihlor's Helm, Harmonium Halbreds, Mercykiller rings, etc. The cost for these items are prohibitively expensive, and the store disables your ability to steal. So only till the late game can you pick em up.
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