The subquests don't seem to have anything to do with chapter. I'm on my 2nd time through the game, and decided to do all of the subquests I can in Chapter 2, and I have most of them done so far. For some reason, they seem to have more dialogue and have a bit more depth when doing them in Ch2 than when I tried to do them after I cleared out the Elf city. I've gotten WAY farther on Nalia's quest than I did before, as in, one father of the jerk that Nalia was suposed to marry has threatoned war on my keep because I woulden't give it to him.
As for Jaheria, so far, I've been listening to her lament over her odds with the Harpers, and in my most recent random run-in with a Harper, she renounced her membership with the Harpers (I'm playing it nice, I'm not butchering all the harpers as they ambush me, I find that I can talk my way out of them attacking).
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