The most you can get is a total of 125 in Crit and that'll actually equate to a 6% chance of causing an instawhack (1% when you get the skill, 1% for every 25 Skill points thereafter). Then level difference, crit resistance, armor, etc. are factored in. If you want to increase chance to hit, Dex, Sen and Str all figure into that equation. Weapon choice can also help, although not a lot of thrown weapons have a very high IK%.
As far as your Valk; close combat skill? And once again, Dex, Sen and Str, and check her load. And level difference.
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