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Muramasa will only appear in the queens chest, and indeed the only way to get new items in there is saving before entering rapax upper castle, do a quick run to the chest, and check if you like what you see.
A chest which most people would say is decently filled with loot as well is the single sentry hut in bayjin (*light*). There are many other chests which can make reloading worthwhile, depending on your goals/etc. (my solo bishop even did a few reloads for the mana stone at he'li).
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