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Buying cheap ammo is only necessary if the shop inventory is full. That happens only very rarely. To throw in a number, i once bought more than 10000 bullet stones from a merchent, and i don't think his list was full before.
Anna only sells a small number of different books, mostly psionic stuff IIRC. I think for alchemist books Kunar (at Umpani Base) is better.
Shops restock three times a day. But it seems to me that the items they refresh are differently for these three restocks. At least when i wait for Kunar to restock books (i usually make a shopping trip to him before i go to trynton), it seems he only stocks new books once a day (together with other items). And i think once a day he only restocks ammo.
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