I had the same problem, Z'ant gets angry, although I didn't know what I did wrong. I guess, there is no way to get him friendly but what you can do is the alliance. Rescue the prisoners and go to Yamir, he will give you an agreement that you give to Z'Ant. Don't speak to him, but only give him that letter, he will give you the tracking device and you get a lot of XP.
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