Muramasa Blade is probably the best one. You can find it as a randomly loaded item in the Rapax Castle (Queen's room to be exact) but if it is not there, you would have to reload the entire area, starting with a saved game before you ever entered in order to try again. I had Ferro make an Ivory blade and I used the Canezou dagger on my Samurai since I missed out on the Murasa Blade and had gone too far to want to reload by the time I learned that it is there or not only when you first enter the area...this makes getting it quite a challenge but from what I remember from previous Wizardry games, it would by far be your best weapon for the Samurai.
Best of Luck,
Moni
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