I don't know if this works in all situations, but with anna in Arnika, I saved before clicking on her to buy. If she didn't have what I wanted, I just reloaded. The inventory changes, even the spell books available.
Of course, once you've bought from that particular inventory, I don't know if the save/reload thing works. Seems to me it didn't when I tried later in the same day. So maybe once you've bought something you have to wait the three sleep periods for a new inventory. But then again, once she's restocked, the save/reload should work until you actually buy something.
judee
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