You can safely advance to Chapter 3. During this chapter, you'll still be able to go to the same places as in no. 2. After that it will be a while before you come back to Athkatla, so it would be best to do the quests during chapter 2 and/or 3 to gain some experience for the tougher chapters.
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The last arrow of Legolas kindled in the air as it flew,
and plunged burning into the heart of a great wolf-chieftain.
All the others fled. -J.R.R. Tolkien, The Lord of the Rings
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