The first two times I forgot to use the potion against the Naga, and the third time I didn't even bother: esp. for the toad village quest the 50% poison res. is very useful.
I read from others the potion can be used to paralyze the Naga, which is useful if you need some time to cure/regroup, but after your first hit she awakes again. (Sounds like Heuristic park never got around to implementing paralysis properly, and just accepted it worked the same as sleep.)
But from role-playing perspective I of course should give you a completely different advice.
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