Stupid muscle memory. I can't remember exactly without actually doing it. However, I know that it is almost exactly like casting a spell on another character in your party. The ctrl button & right click on the character portrait that the potion is targeted to. I believe that the ctrl button will cause the mouse pointer to become the blue targeting circle when over a character portrait.
Use/give button. "Use" highlighted. Scroll to proper potion in window in lower left hand corner. CTRL button and right click on character to benefit from potion.
If I screwed this up, let me know. Then I will only look like an idiot until I try it on the game again. Sheez, I have used potions a thousand times & never really thought about the exact moves.
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