Yes, there are two shops in chapter 6 and one of them sells arrows, bolts, etc. You do have to fight your way through the entrance level to get to the shops, though. You'll need to go down a lift just about due north of the main entrance and I think you then have to do a quest before getting to the shops. If you're low on arrows, you probably should buy some elsewhere.
BTW, neither of these shops buys much of anything. If you have stuff you want to sell, you're stuck with the other shops.
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