My paladin would only have good people in her party, so all good would join. I suppose that once my reputation was over 18, some evil NPC's might not join, but I didn't care about that. I don't know if a neutral will join you if the rep is over 18 either. Any neutrals I had in the party joined before my reputation went above 18.
FYI, my party was:
Me, Paladin
Imoen, Dualed - Thief/Mage
Kivan
Ajantis
Yeslick
Khalid
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