Light Crossbow of Speed + Bolts of Biting + Poison Weapon
Darts of Wounding + Poison Weapon
Poisoned Daggers + Poison Weapon
Asp's Nest + Poison Weapon
Tuigan Bow + Arrows of Biting + Poison Weapon
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These are good in SoA for the most part, but against enemies with good AC, you will want to switch tactics.
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For backstabbing with a 1-H weapon, do not put anything in your off-hand, and have a proficiency in One Weapon Style.
This will increase your chance for a Critical Hit, which will greatly enhance your backstab damage.
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