You can enter the lairs at any time during your period of time in the Underdark. Before you enter Ust Natha, or after you've finished with the city and are on your way back out. Plus, there's plenty of time built in to your Ust Natha quests to visit the lairs one by one.
In the end, it doesn't really matter since she only wants one vial of blood and all three will disappear from your inventory.
Xen, does the Matron Mother's quest really have a time limit to it? I thought it was usually only Phaere's quests.
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\"Though we name the things we know, we do not necessarily know the things we name.\" -Homer W. Smith
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