From what I've heard, Jaheira is willing to romance male Humans, Elves, or Half-Elves, of any class, alignment, or Charisma.
There are hurdles, though: You have to be at (or beyond) certain stages of her quest for her Romance to continue, you have to sleep outdoors every so often, and there's at least one point (in her quest or romance, I forget which) where you have to have a pretty-good Reputation.
With that said, the odds are that you will not complete either the quest or romance, even if you do everything right, because both are notoriously riddled with bugs. Some people report that they've never had problems with it, and some computers can never get it to work. I myself have managed to finish Jaheira's quest and romance--ONCE. After at least a dozen failed attempts.
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Volothamp's Comeuppance
Everything you ever needed to know about the entire Baldur's Gate series......except spoilers.
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