I'm not aware of a shield that is +5 vs. missiles, but I do know of one that is +4.
I like to give the boots of avoidance and the girdle of piercing to the same character. Combined those reduce AC against arrows by 8. But yeah, with that shield +4 that would amount to someone who is invincible to arrows. AC would be in negaitve territory for most fighters to begin anyway, and then subtract an additional 12 for arrows.
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